NMR:
1H NMR (380 K, 500 MHz, DMSO-d6) δ 0.60 (s, 3 H) 0.68 (s, 3 H) 0.74 (t, J=7.34 Hz, 3 H) 1.30 - 1.40 (m, 1 H) 1.46 - 1.58 (m, 2 H) 1.58 - 1.68 (m, 1 H) 1.74 - 1.84 (m, 2 H) 1.92 - 2.09 (m, 2 H) 2.17 - 2.31 (m, 2 H) 2.86 (br s, 1 H) 3.29 - 3.38 (m, 1 H) 3.40 - 3.46 (m, 1 H) 3.78 (s, 3 H) 5.20 (s, 2 H) 6.78 (br s, 1 H) 6.81 - 6.87 (m, 1 H) 6.93 - 7.02 (m, 1 H) 6.96 - 7.00 (m, 2 H) 7.11 - 7.20 (m, 1 H) 7.16 - 7.20 (m, 1 H) 7.33 (br d, J=7.65 Hz, 1 H) 7.48 (s, 1 H).
13C NMR (380 K, 126 MHz, DMSO-d6) δ 12.09 (s, 1 C) 22.39 (s, 1 C) 24.45 (s, 1 C) 28.27 (s, 1 C) 29.41 (br s, 1 C) 32.89 (br s, 1 C) 38.23 (s, 1 C) 42.31 (s, 1 C) 43.09 (br s, 1 C) 44.49 (s, 1 C) 51.27 (br s, 1 C) 56.44 (s, 1 C) 71.45 (s, 1 C) 113.71 (s, 1 C) 115.04 (br d, J=8.17 Hz, 1 C) 116.25 (dt, J=18.62, 8.86 Hz, 1 C) 117.18 - 118.70 (m, 1 C) 121.42 (d, J=4.54 Hz, 1 C) 123.77 (d, J=4.54 Hz, 1 C) 125.28 (br s, 1 C) 127.61 (br d, J=4.54 Hz, 1 C) 130.25 (br s, 1 C) 130.43 (s, 1 C) 135.26 (d, J=12.71 Hz, 1 C) 136.22 (br s, 1 C) 136.77 (s, 1 C) 141.79 (br s, 1 C) 146.79 (d, J=11.81 Hz, 1 C) 151.47 (d, J=242.51 Hz, 1 C) 155.92 (br s, 1 C) 175.33 (s, 1 C), C22 is missing, because of coupling to 19F and line broadening.
19F NMR (380 K, 471 MHz, DMSO-d6) δ -139.47 (br s, 1 F) -126.55 -124.30 (m, 1 F)
